Abstract
The participation of IO 2 in the photosensitized oxidation of 1 − by 1-, 2-, and 1,5-anthracene (A)sulphonates is established by the use of N − 3 as the quencher of the photoreaction. The reaction follows two pathways (i) formation of AO 2 which oxidizes 1 − and (ii) formation of an IO − 2 charge-transfer complex leading to oxidation.
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