Abstract

The dehydrocoupling of PhMeSiH 2 to form oligomers and of PhSiH 3 to form polysilanes has been performed with the precatalyst combination of [Me 2El(C 5H 4) 2MCl 2 (El = Si, C; M = Ti, Zr, Hf) and nBuLi. The results are compared to those produced from (η 5- C 5H 5) 2MCl 2 BuLi .

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