Abstract
The formation kinetics of the ions TMPD + and pyrene + have been studied in pulse irradiated dilute solutions of TPmPD and pyrene in cyclopentane, n-hexane, cyclohexane, methylcyclohexane, iso-octane and cyclo-octane. In cyclohexane and methylcyclohexane the rates of formation indicate rate constants, (7 ± 4) × 10 11 M −1 sec −1 in the case of cyclohexane, for the reaction of solvent positive ions with the solute which are more than tenfold greater than expected for the reaction of molecular positive ions. In the other solvents, however, rate constants on the order of 10 10 M −1sec −1 are found.
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