Abstract

The method of anomalous X-ray diffraction (AXD) was applied to two aqueous electrolyte solutions: 6 m rubidium bromide and 4 m rubidium chloride. Data from the former solution were used to determine Br − hydration and those from the latter to determine Rb + hydration. The results are compared with those obtained from other techniques and contrasted with the hydration of other ions in their respective series. A critical appraisal of the AXD method and its potential for future studies of ionic solutions are given.

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