Abstract

Anomalous wide angle X-ray scattering (AWAXS) is used to investigate the short and medium range order in Sr silicate and Sr aluminosilicate glasses. Strong SrSr correlations at 4 Å are found in the silicate glass, whereas they are much weaker in the presence of aluminium. The first SrO distance and coordination number and further SrSr distances in the silicate glass are consistent with edge sharing octahedra. The SrAl correlations cannot be exactly determined, but the role of charge compensator imposed on the Sr by tetrahedral Al3+ rapidly reduces the order found in the silicate glass.

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