Anomalous temperature behavior of nonlinear dielectric effect in supercooled nitrobenzene

Abstract

Studies of the nonlinear dielectric effect (NDE), describing changes of the dielectric permittivity induced by a strong electric field, in normal and supercooled liquid nitrobenzene are presented. An unusual increase of the stationary NDE, portrayed by the critical-like relation approximately (T-T+)(-1), was obtained. Nitrobenzene samples solidified at TS approximately T+ +2 K , approximately 10 K below the reported melting temperature Tm approximately 278 K . The anomalous increase of the NDE coincided with a slow relaxation process, detected in time-resolved measurements. The results presented offer a reinterpretation of the classical description by Piekara and Piekara [A. Piekara and B. Piekara, C. R. Hebd. Seances Acad. Sci. 203, 852 (1936)] of a positive sign contribution to the NDE in liquids. It is suggested that the obtained anomaly may be associated with the appearance of local quasinematic structures. This is supported by a speculative link to a general model for liquid-liquid transitions [H. Tanaka, Phys. Rev. E 62, 6968 (2000)] and a phenomenological model originally developed for the self-focusing of laser beams [J. Hanus, Phys. Rev. 178, 420 (1969)]. The case of the isotropic-nematic transition in liquid crystalline materials is also recalled. The NDE results reported here are related neither to the glass transition phenomenon nor to the recently developed concept of a second liquid-liquid transition.