Abstract

It is given the theoretical study of some properties of strongly polarizable dielectric crystals in which off-center impurity ions induce ferroelectric phase transition. The spontaneous polarization, transition temperature, soft mode frequency, dielectric susceptibility, ultrasonic attenuation, nuclear spin-lattice relaxation are analyzed. The theory explains observed in K 1− x Li x TaO 3 saturation of remanent polarization with off-center Li + concentration increasing, close to x dependence of phase transition temperature, the anisotropy of ultrasonic attenuation, the absence of anomalies of Li nuclear spin-lattice relaxation rate near T c .

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