Abstract
This paper reports the anomalous infrared spectra of nanometer-sized Fe2O3 particles under certain conditions: some IR absorption peaks obviously shift, theirrelative intensities are changed; all peaks are remarkably broadened; and a broadbackground-absorption band appears. It is suggested that these anomalous IR chac-teristics indicate thata structural phase transition occurs, which results from the polaronic effect due to the increasing of electron-phonon coupling. This effect not only contains the contribution of LO phonons, but also the contribution of softmodes produced by interfacial atoms or molecules.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
