Anomalous flow properties of spherical micelle surfactant solutions passing through small-sized slits

Abstract

The flow properties of complex fluids, such as aqueous solutions of polymers and surfactants, have been investigated in many studies, which revealed interesting and anomalous tendencies for several types of complex fluids in abrupt contraction and expansion flows, such as flows passing through small-sized orifices and slits. In the study, the jet thrust and excess pressure drop (net differential pressure) for experimentally observing their flow properties of water and aqueous solutions of several types of surfactants with spherical micelles in slit flows were measured. Different properties were observed for various surfactant solutions depending on the charge of the solute. The resultant jet thrust and excess pressure drop of cationic and non-ionic surfactant solutions were lower than the experimental values of water. For anionic surfactant solutions, the experimental results were similar to those of water. The types can be arranged as cationic > non-ionic > anionic in order of diminishing the jet thrust and excess pressure drop. Moreover, the effect of strong strain, boundary slip, contraction ratio, size effect, concentration, and interface phenomena was discussed.