Anomalous current-voltage characteristics in organic light-emitting devices

Abstract

Quasi-reversible current maxima at low voltage, leading to N-type current-voltage characteristics with negative differential resistance, have been observed in different types of organic light-emitting devices including conjugated polymer LEDs, dye-doped polymeric LEDs and LEDs from evaporated small molecules. We have investigated the dependence of this phenomenon on different external parameters, like layer thickness, temperature and time. We found that the usual explanations, e.g. by tunneling, cannot satisfactory explain our observations. Instead, our experiments indicate that spatially local effects are responsible for the anomalous high current flow at low voltage. The implications for device operation and lifetime are discussed.