Abstract
1. Complex aluminum hydrides and their alkyl derivatives, in distinction from dialkylaluminum hydrides, add to phenylacetylene mainly anomalously, with formation of styryl aluminum derivatives containing the aluminum atom in the α-position to the phenyl group. 2. Complex aluminum hydrides and their alkyl derivatives add to phenylacetylene nonstereospecifically, giving products of both cis- and also of trans-addition. 3. Nickel salts catalyze the addition of complex aluminum hydrides and their alkyl derivatives to phenylacetylene.
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