Anomalous 182W in high 3He/4He ocean island basalts: Fingerprints of Earth’s core?

Abstract

The short-lived 182Hf-182W isotope system (t1/2 = 9 Ma) left evidence in both ancient and modern terrestrial rock record of processes that took place during the earliest stages of Earth’s accretionary and differentiation history. We report µ182W values (the deviation of 182W/184W of a sample from that of laboratory standards, in parts per million) and corresponding 3He/4He ratios for rocks from 15 different hotspots. These rocks are characterized by µ182W values that range from ∼0 to as low as −23 ± 4.5. For each volcanic system that includes rocks with negative µ182W values, the values tend to be negatively correlated with 3He/4He. The W-He isotopic characteristics of all samples can be successfully modeled via mixing involving at least three mantle source reservoirs with distinct µ182W-3He/4He characteristics. One reservoir has 3He/4He ≈ 8 R/RA and μ182W ≈ 0, which is indistinguishable from the convecting upper mantle. Based on high 3He/4He, the other two reservoirs are presumed to be relatively un-degassed and likely primordial. One reservoir is characterized by µ182W ≈ 0, while the other is characterized by µ182W ≤ −23. The former reservoir likely formed from a silicate differentiation process more than 60 Myr after the origin of the solar system, but has remained partially or wholly isolated from the rest of the mantle for most of Earth history. The latter reservoir most likely includes a component that formed while 182Hf was extant. Mass balance constraints on the isotopic composition of the core suggest it has a strongly negative µ182W value of ∼−220. Thus, it is a candidate for the origin of the negative µ182W in the plume sources. Mixing models show that the direct addition of outer core metal into a plume rising from the core-mantle boundary would result in collateral geochemical effects, particularly in the abundances of highly siderophile elements, which are not observed in OIB. Instead, the reservoir characterized by negative µ182W most likely formed in the lowermost mantle as a result of core-mantle isotopic equilibration. The envisioned equilibration process would raise the W concentration and lower the µ182W of the resulting silicate reservoir, relative to the rest of the mantle. The small proportion (<0.3 %) of this putative core-mantle equilibrated reservoir required to account for the µ182W signatures observed in OIB is insufficient to result in observable effects on most other elemental and/or isotopic compositions. The presumed primordial reservoirs may be linked to seismically distinct regions in the lower mantle. Seismically imaged mantle plumes appear to preferentially ascend from the vicinity of large low-shear velocity provinces (LLSVPs), which have been interpreted as thermochemical piles. We associate the LLSVPs with the primordial reservoir characterized by high 3He/4He and µ182W = 0. Smaller, ultra-low velocity zones (ULVZs) present at the core-mantle boundary have been interpreted to consist of (partially) molten lower mantle material. The negative µ182W signatures observed in some plume-derived lavas may result from small contributions of ULVZ material that has inherited its negative µ182W signature through core-mantle equilibration.