Anodic electrochemical performances of MgCo2O4 synthesized by oxalate decomposition method and electrospinning technique for Li-ion battery application

Abstract

Magnesium cobalt oxide, MgCo2O4 was synthesized by oxalate decomposition method and electrospinning technique. The electrochemical performances, structures, phase formation and morphology of MgCo2O4 synthesized by both the methods are compared. Scanning electron microscope (SEM) studies show spherical and fiber type morphology, respectively for the oxalate decomposition and electrospinning method. The electrospun nanofibers of MgCo2O4 calcined at 650°C, showed a very good reversible capacity of 795mAhg−1 after 50 cycles when compared to bulk material capacity of 227mAhg−1 at current rate of 60mAg−1. MgCo2O4 nanofiber showed a reversible capacity of 411mAhg−1 (at cycle) at current density of 240mAg−1. Improved performance was due to improved conductivity of MgO, which may act as buffer layer leading to improved cycling stability. The cyclic voltammetry studies at scan rate of 0.058mV/s show main cathodic at around 1.0V and anodic peaks at 2.1V vs. Li.