Abstract

In this paper, the performance of several annealing methods on three retired cables and the annealing effects on the improvement in the thermal and electrical properties of cross-linked polyethylene (XLPE) insulation were discussed. The cable insulation layer was peeled, and the peels near the inner semi-conductive layer were used as the test samples. Isothermal treatment and heat recycling treatment were performed at temperatures of 85, 90, 95, and 100 °C, and the temperatures were held in the heat recycling treatment for 8, 16, and 24 h, respectively. Each heat recycling treatment was repeated 20 times, and the duration of the isothermal treatment was the same as that for the heat recycling treatment with a 24 h temperature holding hour. Then, Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) were performed, and the dielectric spectrum, DC conduction current, and dielectric breakdown strength EB were measured. The results showed that damage involving molecular changes is linearly related to the cable service year. As the annealing temperature increases, the melting range and electrical conductivity decrease; the melting point, crystallinity, lamellar thickness, and dielectric breakdown strength increase; and the optimal values appear for the samples annealed at 95 °C. With an increased temperature holding hour, the peels annealed at 95 °C exhibit a decreased melting range and electrical conductivity and an increased crystallinity, melting point, lamellar thickness, and dielectric breakdown strength. As a result, the two different treatments are verified to effectively improve the thermal and electrical properties for the XLPE as early research on cable rejuvenation by heat treatment.

Highlights

  • Cross-linked polyethylene (XLPE) has been widely used as the insulation material in high-voltage cables due to its excellent electrical properties and environmentally-friendly nature

  • The peak at the wavelength of 720 cm−1 corresponds to rocking methylene groups (-CH2), and other three peaks, which appear at 1467 cm−1, 2847 cm−1, and 2924 cm−1, are the most characteristics of XLPE, corresponding to the wag vibration, symmetric stretching vibration, and asymmetric stretching vibration of the CH2 groups, respectively [15]

  • The two peaks appear for only XLPE-15 and XLPE-30, and the absorbance strength is linear with their service year, which strongly evidences that the two samples suffered serious degradation, XLPE-30

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Summary

Introduction

Cross-linked polyethylene (XLPE) has been widely used as the insulation material in high-voltage cables due to its excellent electrical properties and environmentally-friendly nature. To clearly illustrate the differences observed for the samples annealed at 95 ◦C with different Th, Figure 6 shows the melting endotherms of XLPE-0 annealed at 95 ◦C by different heat treatment methods.

Results
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