Abstract

We theoretically explore the scattering properties in collisions between in the ground state and fermionic in the metastable state. Unlike the role of the electronic spin degree of freedom in collisions of two alkali-metal atoms, the orbital degrees of freedom from the p electron of the metastable atoms, which induce not only mixings between different partial waves but also couplings between channels in different fine-structure manifolds, introduce the anisotropic interactions for producing broad-enough Feshbach resonances. Our closed-coupling calculation shows that this mechanism is similar to that in highly magnetic atoms, but the resonances also suffer from a large inelastic rate at the magnitude of to lower-lying fine-structure states or Zeeman sublevels, which will be an obstacle for associating ultracold polar molecules with both electron spin and electric dipole momentum. However, such a rich mixture of inelastic processes, and the experimental advantage of immunity from intraspecies inelastic collisions for metastable fermionic allow for precise investigations on the interspecies scattering properties for systems with excited-state atoms included.

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