Abstract

The weight change of Bi-2212 single-crystalline samples as a function of temperature, time and surrounding atmosphere was investigated by a classical thermogravimetric technique. Clear evidence for a correlation between T c and the c-axis lattice parameter was obtained. A plateau was observed in the dependence of T c and the c-axis lattice parameter on the oxygen contents. From the size dependence it was concluded that oxygen out-diffusion takes place in the a-b plane in a quite anisotropic way, i.e. mainly along the a-direction. At 500°C D a / D b ≥5–6, D ab ≈6.12×10 -8 cm 2/ s.

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