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Abstract
The vibrational spectroscopy has been applied to investigate the structure the BiB3O6 (BIBO) crystal. Based on the experimental results, the total set of phonons mode of the polarized Raman spectra was proposed. To verify the obtained experimental data have been performed theoretical calculation in software package LADY.
Highlights
IntroductionBiB3O6 (BIBO) has excellent optical nonlinear properties for to conversion fervency in the solid state lasers [1]
BiB3O6 (BIBO) has excellent optical nonlinear properties for to conversion fervency in the solid state lasers [1]. It is most effective in the optical range UV and visible light which have widely been used in medicine, signal progressing
Where rij is the interatomic distance and λ and ρ are the parameters characterizing of the short-range pair interionic interaction
Summary
BiB3O6 (BIBO) has excellent optical nonlinear properties for to conversion fervency in the solid state lasers [1]. It is most effective in the optical range UV and visible light which have widely been used in medicine, signal progressing. BIBO have large nonlinear optical coefficient due to its structure and non-hydroscopic nature [2]. Long time thought that BiB3O6 have only alpha phase with space group symmetry C2. More extensively known and studied phase is α-BiB3O6, which build from chain bounded triangles [BO3] and tetrahedrons [BO4] in range 1:2. As α - BiB3O6, β - BiB3O6 consist of chain bounded triangles [BO3] and tetrahedrons [BO4] in range 2:1.
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