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Abstract
On the basis of computations, the (bison) anion is shown to be of interest as a fluorine-free alternative in lithium-conducting electrolytes. Compared to the bison anion has an equally high stability toward oxidation, while at the same time offering a large reduction of the lithium-ion pair dissociation energy. The bison anion is readily available in a number of ambient-temperature ionic liquids (ILs). In this work, the Raman spectrum of the IL reveals an almost unperturbed bison anion and, consequently, the effects of the anion on the Raman shifts of are also very small.
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