Abstract
The controlled polymerization of polar vinyl monomers like acrylic and methacrylic esters is often complicated owing to their chemical structures. As (meth)acrylate polymers are a class of technologically important and useful materials, a great amount of attention has been focused on the polymerization of these monomers is a controlled fashion to give materials with well defined structures and desired properties. This review summarizes recent work on ligated anionic polymerizations of (meth)acrylate esters.
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