Abstract

The polymerization of cyclic lactams (e-caprolactam and ω-dodecalactam) in the presence of anionic initiator and new activators (modifying additives) was studied. The compounds used as modifying additives have the following structures: The effects of the activators on the rate of polymerization, conversion, molecular weight, content of olygomer products, thermal stability were established. The polydispersity of the polyamides obtained in the presence of different activators were investigated.

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