Abstract

The exchange of acyl groups between N-acyllactams or N, N-diacylalkylamines and potassium salts of lactams or N-alkylamides was followed in THF at the initial molar ratio approx. 1:1 in systems either where propagation and other acylation reactions occur or where propagation is excluded and C-acylations are suppressed. The rate of exchange strongly depends on the acidity of the lactam (amide) from which the potassium salt is derived and on the structure of the acyl group.

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