Anionic coordination copolymerization of propylene oxide, carbon dioxide, and l-lactide

Z N Nysenko,V V Rusak,E E Said-Galiev,A M Sakharov,A A Glazkov,M M Ilyin

doi:10.1007/s11172-015-1247-1

Anionic coordination copolymerization of propylene oxide, carbon dioxide, and l-lactide

Z N Nysenko, V V Rusak + Show 4 more

https://doi.org/10.1007/s11172-015-1247-1

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Journal: Bulletin of the Academy of Sciences of the USSR, Division of chemical science	Publication Date: Dec 1, 2015
Citations: 7

Affiliation: N.D. Zelinsky Institute of Organic Chemistry, A. N. Nesmeyanov Institute of Organoelement Compounds

#Copolymerization Of Carbon Dioxide #Copolymerization Of Propylene Oxide + Show 8 more

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Abstract

Terpolymers with various l-lactic acid content in the polypropylene carbonate chain were synthesized by copolymerization of carbon dioxide, propylene oxide, and l-lactide. Zinc adipate was used as a catalyst. Terpolymerization products were characterized by 1H and 13C NMR, 2D {1Н—13С} HMBC, IR spectroscopy, and gel-permeation chromatography. The influence of monomer molar ratio, temperature, and reaction duration on the composition and molecular-mass characteristics of terpolymers was studied. A few questions of terpolymerization mechanism were discussed.

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