Abstract

Organolanthanides with amido-tethered N-heterocyclic carbenes: a new bidentate ligand that tethers an N-heterocyclic carbene group to a trivalent lanthanide complex (samarium, depicted, N′′=N(SiMe3)2; or yttrium) affords the first organolanthanide amido–carbene complexes and an opportunity to explore the strength and reactivity of the early metal–N-heterocyclic carbene fragment.

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