Anion Storing Boron Nitride Hybrid Nanosheets for High-Performance Dual Ion and Zinc Alkaline Full Cells.

Abstract

Hexagonal boron nitride (BN), a well-known member of 2D materials, has a structure similar to graphene and is often referred to as white graphene. Despite its unique physical and chemical properties for energy storage applications, there have been very few studies on how BN stores anion carriers. Herein, the hybrid architecture and anion storage mechanism of BN nanosheets for high-performance hybrid energy storage full cells based on dual-ion and Zinc (Zn) alkaline systems is demonstrated. The chemical bonding between BN and reduced graphene oxide (rGO) is attributed to the formation of the heterointerface, which facilitates the charge transfer kinetics during an OH storing process. Based on the reversible surface redox reaction of BN and rGO hybrid (BN@rGO) confirmed by computational and spectroscopic analyses, the BN@rGO electrode is applied to both Na and OH dual-ion and Zn alkaline full cells. In the dual-ion system, Ti3C2‖BN@rGO full cells extended the operating voltage range up to 1.7V, delivering a cell capacity of 49.4mAhg-1 at 1000mAg-1 and retaining 80% of its initial capacity after 40000 cycles. In the Zn alkaline system, Zn‖BN@rGO full cells achieved a cell capacity of 58.1mAhg-1 at 1000mAg-1 and retained 80% capacity over 90000 cycles.