Abstract
AbstractAs a general outline to show anion guided conformational adjustments of an uncommon conformer found in self‐assembly of 2‐[(5‐methylthiazol‐2‐ylamino)‐methyl]‐phenol (1) and subsequent protonation leading to reversal of conformer is shown. On formation of nitrate salt (1 c) the anti conformer of 1 transformed to syn conformer. Whereas conformational adjustments in the corresponding syn conformer of the organocation of the chloride (1 a) and bromide (1 b) took place to adopt orientations that are different from the parent compound or nitrate salt.
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