Aniline degradation and As (III) oxidation and immobilization by thermally activated persulfate

Abstract

In the Pearl River Delta of China, many sites are likely contaminated with aniline in the soil and arsenic (As) in the groundwater because of a high As background level and the prevailing printing and dyeing industry. This study is to explore the remediation performance of thermally activated persulfate oxidation for the sites with these two contaminants, aniline and As. The As influence on the aniline degradation and vice versa are also systematically investigated. When the molar ratio of aniline to persulfate is 1: 4.65, over 85% of aniline can be degraded at 40 °C in 24 h, and 100 μg L−1 As(III) in solution can be completely adsorbed by the soil. A higher pH favored the aniline degradation but disfavored the As(III) oxidation. Due to the strong buffer capacity of the soil, aniline in the soil could be more quickly degraded than those in the solution. The As(III), however, seem more easily oxidized in the absence of soil. The coexisting Fe2+ can substantially improve As(III) oxidation and immobilization, although the dilute Fe2+ solution may suppress the aniline degradation. The presence of aniline severely inhibited the As(III) oxidation and adsorption, likely due to the competition for the generated free radicals and the adsorption sites on the soils. In contrast, the existing As(III) has a slight effect on aniline degradation. These findings are believed to provide the theoretical basis for the remediation of aniline-arsenic contaminated sites.