Abstract
AbstractThe anharmonicity correction factors for some linear triatomic molecules are estimated by the method of Dennison (1). The potential constants are calculated by means of three different methods — Wilson's F‐G matrix method, Kinetic constants method and L‐approximation method — using the presently evaluated harmonic frequencies. The potential constants thus obtained are utilised in calculating the other molecular constants such as mean amplitudes of vibration, shrinkage effect, compliance constants, Coriolis coupling constants and centrifugal distortion constants for the first time. The results are discussed briefly.
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