Anharmonic IR spectra of solvated ammonium and aminium ions: resemblance between water and bisulfate solvations.

Abstract

In this work, we analyze the vibrational spectra of ammonium, methylammonium, and dimethylammonium ions solvated by either water molecules or bisulfate anions using anharmonic vibrational algorithms. Rich and complicated spectral features in the 2700-3200 cm-1 region of the experimental spectra of these clusters are attributed to originate from strong Fermi resonance between hydrogen-bonded NH stretching fundamentals and NH bending overtones. Additional weaker bands around 2500-2600 cm-1 in solvated aminium ions are assigned to the combination tones involving the CH-NH (methyl-amino) rocking modes. Furthermore, the qualitative resemblance in band positions and spectral patterns between two-water-solvated and two-bisulfate-solvated cations suggest a common vibrational coupling scheme beneath the two seemingly different micro-solvation environments.