Angstrom-to-millimeter characterization of sedimentary rock microstructure

Abstract

Backscatter SEM imaging and small-angle neutron scattering (SANS) data are combined within a statistical framework to quantify the microstructure of a porous solid in terms of a continuous pore-size distribution spanning over five orders of magnitude of length scale, from 10 Å to 500 μm. The method is demonstrated on a sample of natural sandstone and the results are tested against mercury porosimetry (MP) and nuclear magnetic resonance (NMR) relaxation data. The rock microstructure is fractal ( D=2.47) in the pore-size range 10 Å–50 μm and Euclidean for larger length scales. The pore-size distribution is consistent with that determined by MP. The NMR data show a bimodal distribution of proton T 2 relaxation times, which is interpreted quantitatively using a model of relaxation in fractal pores. Pore-length scales derived from the NMR data are consistent with the geometrical parameters derived from both the SEM/SANS and MP data. The combined SANS/BSEM method furnishes new microstructural information that should facilitate the study of capillary phenomena in hydrocarbon reservoir rocks and other porous solids exhibiting broad pore-size distributions.