Anchoring ZnO on spinel cobalt ferrite for highly synergic sono-photo-catalytic, surfactant-assisted PAH degradation from soil washing solutions

Abstract

In this study, the photocatalytic activity of ZnO was effectively improved via its combination with spinel cobalt ferrite (SCF) nanoparticles. The catalytic performance of ZnO@SCF (ZSCF) was investigated in coupling with UV irradiation and ultrasound (US), as a heterogeneous sono-photocatalytic process, for the decontamination of phenanthrene (PHE) from contaminated soil. Soil washing tests were conducted in a batch environment, after extraction assisted by using Tween 80. Several characterization techniques such as XRD, FESEM-EDS, BET, TEM, UV–vis DRS, PL and VSM were utilized to determine the features of the as-prepared catalysts. ZSCF showed an excellent catalytic activity toward degradation of PHE in the presence of US and UV with a significant synergic effect. It was found that more than 93% of PHE (35 mg/L) and 87.5% of TOC could be eliminated by the integrated ZSCF/US/UV system under optimum operational conditions (pH: 8.0, ZSCF: 1.5 g/L, UV power: 6.0 W and US power: 70 W) within 90 min of reaction. After five times of use, ZSCF illustrated good reusability in the decontamination of PHE (87%) and TOC (79%). Quenching tests revealed the contribution of h+, HO• and e− species during PHE degradation over ZSCF/UV/US and an S-scheme photocatalytic mechanisms was proposed for the possible charge transfer routes under the ZSCF system. This study provides the important role of SCF in enhancing the ZnO photocatalytic activity due to its high performance, easy recovery and excellent durability, which it make an efficient and promising catalyst in environmental clean-up applications.