Anchoring Effect of Organosilanes on Hierarchical ZSM-5 Zeolite for Catalytic Fast Pyrolysis of Cellulose to Aromatics.

Abstract

As an essential chemical feedstock, aromatics can be obtained from biomass by catalytic fast pyrolysis (CFP) technology, in which diffusion limitation is still a problem. In this study, several ZSM-5 zeolites with intercrystal stacking macropores were synthesized by adding organosilanes (OSAs) with different alkyl chain groups. Due to the structure-directing effect of the OSA, the prepared ZSM-5 zeolites possess a larger external surface area and pore volume than Blank-Z5. Moreover, the pore size is related to the extent of anchoring of the OSA and silicon–aluminum species in the zeolite precursor. Pyridine Fourier transform infrared (Py-FTIR) and NH3-temperature-programmed desorption (TPD) analyses show that the obtained ZSM-5 zeolites have a higher Brønsted acidity and total number of acid sites. In addition, excessive addition of OSA is not conducive to the growth of ZSM-5 zeolites. The catalytic performance of the synthesized ZSM-5 zeolites was evaluated by Py-GC/MS. The larger external surface area and pore volume improve the accessibility of the acid sites and thus promote the conversion of biomass into aromatics.