Anchored complexes of rhodium and iridium for the hydrogenation of alkynes and olefins with parahydrogen

Abstract

Iridium and rhodium complexes anchored on silica gel surface via NH2–(CH2)3– and P(Ph)2–(CH2)2– linker groups achieve high (∼9%) efficiency in pairwise addition of parahydrogen to unsaturated gaseous substrates in heterogeneous hydrogenation processes.