Abstract

Duplex stainless steel (DSS) has a reasonably high resistance to chloride stress corrosion cracking for offshore and marine applications. However, DSS weld overlay has not been successfully demonstrated due to some inherent problems in achieving pitting and crevice corrosion resistance. In this research work, isothermal heat treatments (350, 650 and 1050 °C) with and different cooling rates have been performed DMR249 Grade A by using shield metal arc welding (SMAW) with an E2209 electrode. Micrographs have shown two phase microstructures of the DSS weld metal, the amounts of austenite phase increased with increment of post-weld heat treatment (PWHT) temperatures. The dilution has maintained consistent values except solution annealing that has shown the disappearance of the heat affected zone in micrographs. The weld metal hardness values increased with PWHT temperatures and remained low at solid solution annealing temperatures. The major alloying elements (C, Mo, Cr, Ni, N, and Fe) were analyzed, as these elements can contribute to intermetallic phases. The results showed that C and Cr content slightly increased with PWHT except for solid solution annealing, Mo showed consistently low content due to dilution effects. Ni maintained higher content, although the heat-treated samples showed slight fluctuations. Nitrogen produced consistent values, as recommended to prevent critical involvement in nitride precipitation.

Highlights

  • In the petrochemical and oil & gas industries, most corrosion-resistant alloy weld overlays are clad with austenitic stainless steel or high nickel alloys

  • The solidification modes can be determined by using chromium equivalent (Creq ) and nickel equivalent (Nieq )

  • Isothermal heat treatments in the range 350–1050 ◦ C with various holding times and different cooling rates have been performed on Duplex stainless steel (DSS) weld overlays on carbon steel substrates

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Summary

Introduction

In the petrochemical and oil & gas industries, most corrosion-resistant alloy weld overlays are clad with austenitic stainless steel or high nickel alloys. DSS weld overlays have not been successfully demonstrated due to some inherent problems to achieve resistance to pitting and crevice corrosion caused by the intermetallic precipitations in the heat-affected zone. DSS is typically manufactured in annealed conditions because it has a high content of alloying elements, such as chromium, molybdenum, and nitrogen. Their structures are generally consisted of austenite (γ) (face-centered cubic structure) and ferrite (body-centered cubic structure) [2]. An alternative method to improve the material’s pitting corrosion resistance with reliable and affordable cost is using corrosion resistant alloy (CRA) cladding, whiech has been demonstrated to be more cost effective, considering the higher strength, better long-term reliability and light weight [3]

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