Abstract
The analytically solvable model for kinetics of luminescence instantaneous spectra and anisotropy of spherical dipole molecules of inhomogeneous ensemble in a polar liquid solution is presented. The experimental results obtained by means of selective kinetic spectroscopy technique are explained. They are the shift of emission spectra and nonexponential behaviour of emission anisotropy due to relaxation processes in solvates. Some new effects are predicted. Among them: ordering of the excited molecules orientation at the certain stages of relaxation and exceeding of the Levshin-Perrin theory limit.
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