Abstract
Upgraded coal-derived liquids obtained from catalytic hydroprocessing of a 30–70(wt%) blend of SRC-1 with SRC-II have been studied by infrared and proton magnetic resonance spectroscopy, and gel permeation chromatography techniques. Compared with the feed blend, the upgraded liquids exhibit a lower C H ratio and decreased aromatic, heteroatom and pentane-insoluble contents, along with decreased specific gravity and viscosity. The amount of hydrogen-bonded structure in the upgraded liquid decreases with increases in residence time and processing temperature. The pseudo-first-order disappearance of phenolic OH and total nitrogen during processing indicates a relative reactivity of 2:1 of hydroxyl oxygen removal to total nitrogen removal in the upgrading process. Conversion of pentaneinsolubles to soluble oil also follows a pseudo-first-order reaction; under mild processing conditions, the heteroatom functionalities play a dominant role in the ease and extent of this conversion. Higher temperatures increase thermal cracking and hydrocracking of the ring structure resulting in more conversion of asphaltene to oil. The linear dependence of the logarithm of viscosity on the content of heteroatoms and toluene-insolubles (TI) indicates the importance of molecular interactions involving polar functional groups in defining the viscosity of coal-derived liquid.
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