Abstract
AbstractFor copolymerization of styrene or methyl methacrylate with N‐p‐tolylcitraconimide (in toluene) or fumarodinitrile (in benzene) at 60°C with 2,2′‐azoisobutyronitrile (AIBN) as initiator, the composition of the resulting copolymers was measured as a function of the monomer feed composition. To provide good accuracy of reaction modelling in terms of the terminal and penultimate models, the linearized forms of both models were applied assuring high sensitivity of the evaluation. Among the systems considered the styrene/fumarodinitrile system with r′1/r′1 ≈ 10 was found to copolymerize according to the penultimate mechanism to a significant degree.
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