Abstract
ABSTRACT Superstoichiometric oxygen combustion (i.e. the oxygen content during combustion is larger than required for the complete conversion of the fuel), also called pure-oxy-fuel, is a novel concept to reduce CO2 emissions from the cement clinker production. In the current contribution, we examine in a simulation study the influence of superstoichiometric combustion in combination with the use of refuse-derived fuel (RDF) of different composition and particle size on process parameters and cement clinker quality in the rotary kiln. A comparison with a standard fuel, namely lignite, and a conventional air-fired kiln is presented. The specific models developed to determine the flight and combustion behavior of RDF particles, which are of complex shape and significantly larger than pulverized coal, are described. The simulations conducted show that some RDF fractions react only partially in the gas phase due to their relative large size. Unburnt RDF particles reach the clinker bed, where they continue to react. In addition, for RDF, gas-phase temperature and the clinker temperature are different along the kiln length compared to coal, influencing the local mineralogical reaction in the clinker bed. However, in summary, similar clinker qualities could be obtained also compared to a standard air-fired kiln.
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