Abstract
The title monomer was synthesized and polymerized using free radical initiation. The polymerization was facile and proceeded rapidly to high conversion. The high field 13C-NMR and 1H-NMR spectra of the polymer had several signals that displayed sensitivity to polymer stereochemistry. Analysis of these signals showed poly(2,5-dimethyl-3-vinyl thiophene) to be an atactic polymer.
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