Analysis of SBS content quantitative determination and rheological properties of aged modified asphalt binder

Abstract

The content of styrene–butadiene–styrene (SBS) modifier has a significant influence on the physical and chemical characteristics of asphalt. However, determining the SBS content in SBS modified asphalt (SBS MA) after aging remains a challenge. To facilitate the understanding of the relationship between physical properties and SBS content, the Fourier transform infrared (FTIR) and potentiometric titration test were utilized to detect SBS content of aged binders. In this paper, radial and linear SBS were incorporated into asphalt binders at three levels, and their rheological properties were investigated after thin film oven aging (TFOT) and long-term aging. Furthermore, the actual SBS content versus the rheological index at different aging stages was investigated. The results showed that both IC=C and Na2S2O3 titration volume highly correlated with SBS content (R2 > 0.99), and there was only a slight difference between the actual content of SBS determined by the two methods. The fatigue resistance, high-temperature elastic, and low-temperature cracking characteristics of asphalt were weakened after aging, due to SBS degradation, especially in the early stage. In addition, the resistance to deformation, elastic recovery, anti-fatigue properties of radial SBS MA were superior to that of linear SBS MA at the same SBS content, while the low-temperature cracking performance demonstrated an opposite trend. The actual SBS content versus the rheological indexes after aging can be well-fitted by a nonlinear equation. Therefore, FTIR and potentiometric titration tests can effectively predict SBS content and analyze the aging degree of SBS MA.