Abstract

Utilization of wastes for the preparation of ceramic foams has gradually become a major direction in the development of new building materials. In this paper, all wastes-based ceramic foams based on electrical insulators waste (EIW) and red mud (RM) were prepared through the high-temperature foaming method. The factors affecting the increase in pore size under different preparation conditions (RM content, temperature and time) were investigated separately by studying the changes in pore size. With the increase of RM content, sintering temperature and sintering time, the pore morphology gradually evolved from a regular spherical shape to a polygonal or irregular shape with a corresponding increase in pore size, albeit at different rates. The pore size enhancement ascribed to changes in RM content was primarily attributed to the synergistic influences of a plurality of factors including glass phase content, viscosity, and gas phase content. Sintering temperature mainly affected the balance between the forces acting inside and outside the pores and the gas phase solubility in the liquid phase to adjust the size of pores. The influence of sintering time on pore size and morphology emanated from the glass phase viscosity and the resulting changes in the release rate of gas phase. In summary, the study will help to investigate the actual controlling factors of composition and process on the pore structure, and provides significant insights into the optimization and adjustment of pore structure for samples obtained by high-temperature sintering.

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