Abstract
AbstractPolymerization rates in radical polymerization of methyl methacrylate initiated by 2,2′‐azobis(2,4‐dimethyl valeronitrile) under various conditions were analyzed by using a previously derived simple equation. The results obtained are discussed on the basis of the relation of solvent viscosity and temperature. It is concluded that chain termination rate constant is inversely proportional to the solvent viscosity, but primary radical termination rate constant can not be related immediately to solvent viscosity.
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More From: Journal of Polymer Science Part A-1: Polymer Chemistry
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