Analysis of particles containing alpha-emitters in stagnant water at torus room of Fukushima Dai-ichi Nuclear Power Station’s Unit 2 reactor

Abstract

Particles containing alpha (α) nuclides were identified from sediment in stagnant water in the torus room of the Fukushima Dai-ichi Nuclear Power Station(FDiNPS)’s Unit 2 reactor. We analyzed uranium (U), which is the main component of nuclear fuel, using scanning electron microscopy (SEM). Other α-nuclides (plutonium [Pu], americium [Am], and curium [Cm]) were detected by alpha track detection and the morphology of particles with α-nuclides were analyzed by SEM-energy dispersive X-Ray (EDX) analysis. Several uranium-bearing particles ranging from sub-µm to several µm in size were identified by SEM observation. These particles contained zirconium (Zr) and other elements which constituted fuel cladding and structural materials. The 235U/238U isotope ratio in the solid fractions that included U particles was consistent with what was found for the nuclear fuel in the Unit 2 reactor. This indicated that the U of similar fuel composition had made finer. The α-nuclide-containing particles identified by alpha track analysis were several tens to several hundred µm in size. The EDX spectra showed that these particles mainly comprised iron (Fe). Since the amount of α-nuclide material was very small, Pu, Am, and Cm were adsorbed on the Fe particles. This study clarifies that the major morphologies of U and other α-nuclides in the sediment of stagnant water in the torus room of FDiNPS’s Unit 2 reactor differed.