Abstract

A careful study of aqueous sodium fluoride solutions was carried out by the electrocapillary method. Detailed attention was given to the adsorption behaviour in dilute solutions and the results are compared with published work. Causes of discrepancies in interfacial tensions obtained directly and indirectly are examined, and found to be significantly reduced by application of appropriate experimental procedures. Localized hydrolysis and complexation effects of mercurous ions are proposed as sources of inconsistent double-layer results by different experimental approaches.

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