Abstract
We study external quantum efficiency (ηEQE) roll-off in organic light-emitting diodes (OLEDs) using thermally-activated delayed fluorescence (TADF) of 4,5-di (9H-carbazol-9-yl) phthalonitrile (2CzPN). Using 2CzPN intramolecular rate constants from optical analyses, we construct an exciton quenching model incorporating intersystem crossing and reverse intersystem crossing. The model indicates that singlet–triplet annihilation and triplet–triplet annihilation dominate ηEQE roll-off because of the relatively long 2CzPN triplet lifetime of 273μs. This work yields a method to relax the exciton quenching process in TADF based OLEDs.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
