Analysis of enrichment, correlation, and leaching patterns of rare earth elements in coal fly ash assisted by statistical measures

Abstract

Coal fly ash (CFA) is a typical industrial solid waste, which has recently been reported to contain rare earth elements (REEs). REEs are important materials in many industrial fields. Therefore, extracting REEs from CFA becomes a win-win strategy to both make full use of CFA and reclaim REEs. However, the stable crystalline structure of CFA is hard to break, which limits the extraction of REEs. The inter-correlation and the leaching patterns of the REEs in CFA also remain unclear. In this work, REEs were enriched by desilication, and the correlation and the influences of multiple acids of the leached REEs were investigated. It was found that desilication could increase the leachable amount of REEs from 137.37 ppm to 346.12 ppm. The light rare earth elements (LREEs) were less inter-correlated than heavy rare earth elements (HREEs) and desilication enhanced the leaching of LREEs more than that of HREEs. The ratio and type of the leaching acids both influenced the extraction of REEs from CFA: HCl and HF played important roles in the extraction from the untreated CFA while HNO3 and HF were more decisive for the desilicated CFA. In addition, we used statistical analysis to quantificationally confirm that desilication and acids both significantly influenced the extraction of REEs. This work provides evidence for the enrichment of REEs in CFA and acid choosing when leaching REEs from CFA.