Analysis of dopant atom distribution and quantification of oxygen vacancies on individual Gd-doped CeO2 nanocrystals.

Abstract

This work reports the analysis of the distribution of Gd atoms and the quantification of O vacancies applied to individual CeO2 and Gd-doped CeO2 nanocrystals by electron energy-loss spectroscopy. The concentration of O vacancies measured on the undoped system (6.3±2.6 %) matches the expected value given the typical Ce(3+) content previously reported for CeO2 nanoparticles. The doped nanoparticles have an uneven distribution of dopant atoms and an atypical amount of O vacant sites (37.7±4.1 %). The measured decrease of the O content induced by Gd doping cannot be explained solely by the charge balance including Ce(3+) and Gd(3+) ions.