Abstract

Mine water discharges can cause negative effects on recipient rivers. The magnitude of the effects depends on how quickly and efficiently contaminants dilute in the river. Electrical conductivity (EC) is linked to the water quality and can be utilized as a general tool to compare and detect the contaminant sources and concentration changes derived from mine water discharge. Hydrological and flow velocity profiling devices were tested to assess the impact as well as mixing and dilution of mine effluent discharge in a river next to a gold mine in Finland. Additionally, flow rate and velocity profiles of the cross-sections were measured. Recently, the greatest ecological impacts had been detected in the vicinity of the dewatering discharge point, which has the highest sulphate concentrations in rivers. According to EC measurements of this study, these were the same locations, where the mine effluent did not dilute and mix efficiently due to lower flow velocities and lesser turbulence. Further, EC values displayed a significant positive correlation with sulphate, magnesium, potassium, sodium, and calcium, whereas a lower correlation was observed with the trace elements. The tested study method revealed how changes in the river morphology and flow velocity affect behaviour, mixing, and dilution processes. Mixing and dilution of contaminants depended on the discharge location and method as well as on the density differences between the mine water discharge and fresh river water. This study highlights the importance of detailed hydrological and flow rate measurements when designing the location of mine water discharge to recipient rivers.

Highlights

  • Mine water discharges are recognized as being responsible for the greatest environmental impact of mining (Environmental Law Alliance Worldwide 2010)

  • Electrical conductivity (EC) values displayed a significant positive correlation with sulphate, magnesium, potassium, sodium, and calcium, whereas a lower correlation was observed with the trace elements

  • The results show that in the vicinity of mine process effluent water and dewatering water discharge locations (Fig. 5) sulphate concentrations are higher than the Canadian water quality criteria for soft to moderately soft water (CCME 2014)

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Summary

Introduction

Mine water discharges are recognized as being responsible for the greatest environmental impact of mining (Environmental Law Alliance Worldwide 2010). The occurrence and concentrations of harmful metals, sulphates, and nutrients can be linked to the geology and mineralogy of the ore deposit and to the water treatment efficiency and the chemicals used in mineral beneficiation. The acidity of the metal-rich mine drainage has been accounted for as the main contributor to adverse impact on freshwater. The role of secondary salinisation and elevated sulphate concentrations have found to play important role in degradation of freshwater ecosystems (Cañedo-Argüelles et al 2013; Porter-Goff et al 2013; Zhao et al 2017). Recent research shows that elevated sulphate concentrations increase phosphate availability and mobility from sediment and susceptibility to eutrophication as well as mercury mobilization through methylation (cf. Meays and Nordin 2013), yet there are no water quality guidelines for sulphate concentrations in surface waters in most of countries

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