Abstract
AbstractValence XPS studies of well oriented polyethylene mats, deposited on a gold substrate, provide direct evidence of the existence of the fold structure at the sample surface and confirm earlier suggestions that conformation is directly fingerprinted in that energy region of the spectra. These results also provide new insight into the origin of the valence XPS spectra differences, so far unexplained, of n‐tridecane recorded in gas and solid phase.
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