Abstract
A sodium-ammonia tetraborate Na1.33(NH4)0.67B4O5(OH)4·(H2O)2 (denoted 1) has been synthesized under mild solvothermal condition. The compound crystallizes in the chiral trigonal R32 (155) space group, with the following unit cell parameters: a = 11.172(3) A, b = 11.172(3) A, c = 21.282(10) A; V = 2300.4(14) A3; Z = 3. It has been characterized by single crystal X-ray analysis, element analysis, FTIR, PXRD, TG-DSC and Second-harmonic-generation response. Its structure contains [B4O5(OH)4]2− polyanions, which are further linked by a rare [Na4O18] cluster to form a 3-D framework.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
