Abstract
A novel cuprous iodide polymer [Cu2(μ4-L)(μ2-I-)(I2)(I3-)]n·nI2 (1, L = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized. 1 contains a 1-D chain [Cu2(μ4-L)(μ2-I-)(I2)(I3-)]n and free I2 molecules, which are interconnected by weak II interactions to form an unprecedented 3-D cuprous polyiodide network containing rare 1-D [(I-)·2I2·(I3)-]n polyiodide ribbons. 1 shows luminescence and photoelectronic properties, and its theoretical band structure was also studied.
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